Histry Chem

Conhecimento

MSDS for Succinic Dihydrazide

Identification

Product Name: Succinic Dihydrazide
Chemical Formula: C4H8N4O2
Synonyms: Butanedihydrazide, Succinic acid dihydrazide
Manufacturer: Detailed manufacturer and supplier contact, including emergency contacts, need to appear here for clear communication in case of chemical emergencies.
CAS Number: 108-31-6
Recommended Use: Research, intermediate in chemical synthesis, possibly industrial application in pharmaceutical and chemical processing.

Hazard Identification

Classification: Not recognized as acutely hazardous under GHS. May cause irritation to eyes, skin, and respiratory tract upon direct, repeated, or prolonged exposure.
Label Elements: Not subject to specific hazard pictograms, but gloves, goggles, and respiration aids can prevent contact.
Hazard Statements: Direct contact irritates. Dust may trigger coughing or shortness of breath if inhaled.
Precautionary Statements: P264 - Wash hands thoroughly after handling. P280 - Wear protective gloves and eye protection.
Health Hazards: Repeated skin contact may cause redness, dryness, or cracking. Long-term exposure has not shown significant evidence for chronic effects, but overtreat as a general chemical irritant.

Composition / Information on Ingredients

Chemical Identity: Succinic Dihydrazide
CAS Number: 108-31-6
Concentration: Generally supplied in >98% pure forms, trace solvent residues possible
Other Components: No known additives or stabilizers under standard commercial distribution.

First Aid Measures

Eye Contact: Flush eyes with lukewarm water for at least 15 minutes, hold eyelids open, seek medical advice if irritation remains persistent.
Skin Contact: Wash area with soap and running water. Remove contaminated clothing immediately. Contact a physician if rash or irritation continues.
Inhalation: Move to open air. Call medical personnel if breathing discomfort does not improve.
Ingestion: Rinse mouth thoroughly. Don’t induce vomiting. Contact poison control or emergency department for further guidance.

Fire-Fighting Measures

Flammability: Not classified as flammable, but may produce hazardous gases if involved in fire.
Extinguishing Media: Suitable media include water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Select method appropriate to surroundings.
Specific Hazards: Combustion could create nitrogen oxides, carbon monoxide, irritating fumes, and potentially toxic gases.
Protective Equipment for Firefighters: Wear self-contained breathing apparatus and full protective gear.
Additional Advice: Stay upwind, keep unnecessary personnel away, and cool exposed containers with water if safe to do so.

Accidental Release Measures

Personal Precautions: Use appropriate personal protective equipment including eye protection, gloves, and dust masks. Avoid breathing in dust or contact with skin/eyes.
Environmental Precautions: Prevent uncontrolled entry to drains, surface water, or soil.
Spill Cleanup Methods: Collect spilled material with non-sparking tools. Place spill waste in sealed, labeled container. Ventilate affected area and wash spill site after collection complete.

Handling and Storage

Safe Handling: Ensure good ventilation in working space. Minimize direct handling by using sealed containers, tools, or transfer lines.
Hygienic Practices: Wash hands and exposed skin with soap and water after contact. Remove contaminated clothing before breaks.
Storage Recommendations: Store in cool, dry, well-ventilated areas away from direct sunlight and incompatible chemicals like strong oxidizers or acids. Keep container tightly closed to minimize moisture uptake and contamination risks.

Exposure Controls and Personal Protection

Exposure Limits: No established occupational exposure limits. Exercise general comfort limits for non-volatile dusts.
Engineering Controls: Where powder or dust generation occurs, install local exhaust ventilation. General mechanical ventilation suffices for routine handling.
Personal Protective Equipment: Chemical-resistant gloves (nitrile recommended), safety goggles, and standard laboratory coats. Use P2/P3 particulate respirator if dust becomes airborne and ventilation isn’t adequate.
Workplace Hygiene: No eating, drinking, or smoking in chemical handling areas.

Physical and Chemical Properties

Appearance: White to off-white crystalline powder
Odor: Odorless, or slight characteristic chemical smell
Molecular Weight: 132.13 g/mol
Melting Point: About 186°C (367°F)
Solubility: Slightly soluble in water, more soluble in warm water
pH: Neutral to slightly alkaline in solution
Boiling Point: Not applicable (decomposes before boiling)
Flash Point: Not applicable under typical use conditions
Vapor Pressure: Negligible at room temperature
Density: Around 1.5 g/cm³ at 20°C
Partition Coefficient: Not determined
Evaporation Rate: Non-volatile solid

Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling situations. No evidence of violent decomposition under mild environmental conditions.
Reactive Risks: May react with strong oxidizers or acids; avoid generating dust-air mixtures due to possible ignition risk.
Conditions to Avoid: Strong heat, open flames, direct sunlight, incompatible chemicals
Decomposition Products: Nitrogen oxides, hydrazine derivatives, carbon monoxide, carbon dioxide, and potentially noxious fumes under fire.

Toxicological Information

Routes of Exposure: Skin and eye contact, inhalation of dust, or accidental ingestion
Acute Effects: Primary irritation to eyes, skin, and upper respiratory tract. Ingestion of significant amounts may cause nausea or abdominal discomfort.
Chronic Effects: No specific long-term toxicity data available for this compound; handle all hydrazide derivatives as potential health hazards based on chemical category.
Sensitization: Not reported, but avoid repeated skin contact as standard precaution.
Carcinogenicity: No classification by IARC, NTP, or OSHA.
Mutagenicity/Teratogenicity: Not investigated in detail for this particular compound.

Ecological Information

Aquatic Toxicity: No measured acute aquatic toxicity data, but avoid discharge into waterways.
Persistence and Degradability: Expected to be stable in the environment; detailed breakdown pathways not documented.
Bioaccumulation Potential: No evidence of significant bioaccumulation.
Soil Mobility: Expected to be relatively immobile due to limited water solubility.
Other Adverse Effects: Avoid environmental contamination with any synthetic chemicals.

Disposal Considerations

Waste Treatment Methods: Collect material and place in chemically compatible, labeled drums for commercial chemical waste contractor disposal.
Contaminated Packaging: Triple rinse containers, then puncture and dispose similarly or recycle if legally permitted.
Hazardous Waste Codes: Not classified under RCRA.
Additional Advice: Never dispose via public sewers, surface water, or household waste channels.

Transport Information

UN Number: Not regulated for ground or air transport under current UN, IMDG, or IATA rules.
Proper Shipping Name: Succinic Dihydrazide
Transport Hazard Class: No assigned class
Packing Group: No required packing group
Environmental Hazards: Not classified as marine pollutant
Special Precautions: Keep drums or containers well sealed and cushioned against rough handling or tipping.

Regulatory Information

Regulatory Status: Not listed under major chemical inventories such as TSCA, REACH, or DSL as hazardous.
International Regulations: Compound appears on EINECS, not subject to special reporting under US SARA, CERCLA, or other federal statutes.
Labeling Requirements: No extraordinary labeling, but workplace containers should reference contents and safe handling requirements at all times.
Workplace Exposure Registration: Recommended for comprehensive occupational risk records whenever in repeated, continuous, or bulk use scenarios.