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Material Safety Data Sheet: Suberic Acid

Identification

Product Name: Suberic Acid
Synonyms: Octanedioic Acid, 1,6-Hexanedicarboxylic acid
Chemical Formula: C8H14O4
CAS Number: 505-48-6
Recommended Uses: Used in the production of plasticizers, resins, and perfumes. In industrial settings, often involved in nylon synthesis and specialty chemical formulations.
Supplier: Contact information of regional manufacturers or chemical distributors. Include emergency contact number on every label and database entry.

Hazard Identification

GHS Classification: Eye Irritant (Category 2A), Skin Irritant (Category 2)
Signal Word: Warning
Hazard Statements: Causes serious eye irritation, can cause mild skin irritation after direct and prolonged skin contact.
Precautionary Statements: Avoid breathing dust or mist, wash thoroughly after handling, wear eye protection, wash hands before eating or drinking.
Label Elements: Exclamation mark pictogram used for irritant classification.
Most Important Symptoms: Redness and pain in eyes or skin, possible respiratory discomfort in poorly ventilated environments.

Composition / Information on Ingredients

Chemical Name: Suberic Acid
Concentration: Greater than 99% (technical grade and higher Purity product)
Impurities: May contain trace amounts of related dicarboxylic acids, water, and inorganic residues due to manufacturing.
Additives: No additives used in certified pure grades.

First Aid Measures

Eye Contact: Immediately rinse with plenty of water for several minutes, remove contact lenses if present and easy to do, continue rinsing, seek medical attention for persistent symptoms.
Skin Contact: Wash skin thoroughly with soap and water. Remove contaminated clothing and launder before reuse. If irritation persists, get medical advice.
Inhalation: Move person to fresh air, keep at rest in a position comfortable for breathing, seek medical attention if symptoms develop.
Ingestion: Rinse mouth, do not induce vomiting unless directed by medical professionals, seek medical care if you feel unwell.
Note for Physicians: Treat symptomatically based on patient’s current signs and act quickly to prevent further absorption.

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, alcohol-resistant foam, dry chemical powder, carbon dioxide.
Specific Hazards: Can form combustible dust concentrations in air. Decomposes on heating to release carbon oxides.
Protective Equipment for Firefighters: Self-contained breathing apparatus and full protective clothing required.
Firefighting Instructions: Approach fire from upwind to avoid hazardous vapors. Cool containers exposed to fire with water spray. Remove unaffected materials from fire area if safe to do so.

Accidental Release Measures

Personal Precautions: Use personal protective equipment including gloves, goggles, and dust mask. Evacuate non-essential personnel and ventilate area.
Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not allow entry into sewers or watercourses.
Methods for Cleaning Up: Sweep up and place in suitable closed containers for disposal. Use damp cloth or vacuum to reduce dust dispersal. Wash area with water after removal.

Handling and Storage

Handling: Keep away from heat, sparks, and open flame. Use only in well-ventilated areas. Avoid contact with eyes, skin, and clothing. Do not eat, drink, or smoke near handling areas. Avoid creating and breathing dust.
Storage: Store in tightly closed, labeled containers in a cool, dry, and well-ventilated area away from incompatible materials such as strong oxidants or bases. Place containers in secondary containment to prevent spillage.
Incompatibles: Reacts with strong bases and oxidizing agents. Avoid storing with acids and alkalis in close proximity.

Exposure Controls and Personal Protection

Occupational Exposure Limits: No specific regulatory limits established for suberic acid, but control dust as for nuisance particulates.
Engineering Controls: Provide local exhaust ventilation or enclosure to control airborne dust concentrations. Use enclosed processes or isolation when feasible.
Personal Protective Equipment: Safety glasses with side shields or goggles, chemical-resistant gloves (such as PVC or nitrile), long sleeves and trousers. Use a dust respirator where dust exposure can accumulate above safe levels. Wash hands and face after handling.
Hygiene Measures: Remove contaminated clothing before leaving work area. Do not eat, drink, or smoke in work areas where substance is handled.

Physical and Chemical Properties

Appearance: White crystalline solid
Odor: Odorless or slight carboxylic acid scent
pH (5% solution): Slightly acidic
Melting Point: 141–143°C (285–289°F)
Boiling Point: Decomposes before boiling
Flash Point: Not easily flammable, but dust-air mixtures can ignite
Solubility: Slightly soluble in water and soluble in boiling water, soluble in alcohol and ether
Vapor Pressure: Negligible at room temperature
Density: 1.28 g/cm³
Partition Coefficient (log Kow): Approximately -1.29

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions. Will decompose at high temperatures producing fumes of carbon oxides.
Conditions to Avoid: Moisture, heat, ignition sources, and incompatible chemicals such as strong oxidants and alkalies.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, and potentially irritating organic vapors upon combustion or thermal decomposition.
Polymerization: Not known to occur under normal handling conditions.

Toxicological Information

Routes of Exposure: Eyes, skin, inhalation, and ingestion
Acute Effects: Eye and skin irritation, mild respiratory tract discomfort after inhaling significant concentrations of dust.
Chronic Effects: No evidence of long-term health effects or sensitization provided exposure is controlled. No data indicating carcinogenicity, mutagenicity, or reproductive toxicity.
LD50 (oral, rat): >5000 mg/kg (low acute toxicity)
Symptoms: Redness, pain, possible coughing or mild nausea if inhaled or ingested in significant quantities.

Ecological Information

Ecotoxicity: Not expected to be toxic to aquatic organisms at low concentrations. Biodegradation in soil and water occurs, but best to limit contamination.
Persistence and Degradability: Biodegradable in the environment by natural microbial activity.
Bioaccumulative Potential: Low (log Kow indicates low bioaccumulation harm)
Mobility in Soil: Expected to exhibit moderate mobility depending on local conditions.
Other Adverse Effects: Poorly soluble acids may acidify water slightly if discharged in bulk, which can disrupt local pH.

Disposal Considerations

Waste Disposal Methods: Collect and contain in appropriate containers for landfill or incineration at an approved facility. Never pour waste into drains or sewers.
Contaminated Packaging: Clean and reuse where possible or dispose as hazardous chemical waste according to local, national, and regional regulations.
Precautions: Avoid creating dust during disposal, ensure proper labeling on all disposal containers, and prevent environmental contamination during transfer.

Transport Information

UN Number: Not regulated as a hazardous material for ground, air, or sea transport under UN, IMDG, IATA, or DOT guidelines for most industrial applications.
Proper Shipping Name: Suberic Acid, solid
Transport Hazard Class: Not classified as dangerous
Packing Group: Not applicable
Special Precautions for Transport: Keep cargo securely packaged to avoid shifting and dust generation, protect from moisture, separate from reactive substances.

Regulatory Information

TSCA (US): Listed
EINECS (EU): 208-003-4
DSL (Canada): Listed
REACH (EU): Pre-registered and compliant for industrial use
OSHA HazCom: Regulated for labeling and safety data sheet requirements.
SARA Title III: Not subject to reportable quantities.
Other International Inventories: Check applicable country-specific databases for latest compliance updates.