Histry Chem

Conhecimento

MSDS for Octyl Decyl Acrylate

Identification

Product Name: Octyl Decyl Acrylate
Chemical Formula: C19H36O2
CAS Number: 24620-21-3
Synonyms: 2-Propenoic acid, C8-10-alkyl esters
Recommended Uses: Industrial monomer for coatings, adhesives, inks, and paints
Supplier Identification: Provided by manufacturer on package label
Contact Information: Emergency phone numbers and local regulatory contact details included on product packaging
REACH Registration Number: Information provided by distributor or manufacturer for European Union requirements
Date of Issue/Revision: Check product documentation

Hazard Identification

Hazard Classification: Eye irritation (Category 2), Skin sensitization (Category 1), Aquatic chronic hazard (Category 2)
Label Elements: GHS hazard pictograms (exclamation mark, aquatic environment)
Signal Word: Warning
Hazard Statements: Causes skin and eye irritation, may cause allergic skin reaction, toxic to aquatic life with long lasting effects
Precautionary Statements: Avoid skin and eye contact, do not breathe vapors, wash thoroughly after handling, avoid release to environment
Route of Exposure: Inhalation, skin and eye contact
Health Effects: May lead to skin redness, rash, eye discomfort or watering, respiratory irritation
Physical Hazards: Flammable liquid and vapor; reacts with heat, light, and strong oxidizers

Composition / Information on Ingredients

Chemical Name: Octyl decyl acrylate
CAS Number: 24620-21-3
Concentration: 95 - 100% by weight
Impurities: May contain trace hydroquinone or polymerization inhibitors
Other Constituents: Inert or trade secret stabilizers present below regulatory disclosure thresholds

First Aid Measures

Inhalation: Move affected person to fresh air, allow comfortable breathing. Seek medical attention for symptoms like cough, dizziness, or respiratory distress.
Skin Contact: Remove contaminated clothing. Wash area thoroughly with soap and water. If a rash or irritation develops, get medical advice.
Eye Contact: Rinse eyes cautiously with water for several minutes, remove contact lenses if present and easy. Keep eyelids open, seek ophthalmologist if irritation persists.
Ingestion: Rinse mouth with water but do not induce vomiting. Seek immediate medical help.
Most Important Symptoms: Skin sensitization, redness, swelling, potential respiratory irritation or asthma-like reactions
Notes to Physician: Treat symptomatically, monitor for allergic reactions, consider observation for delayed effects

Fire-Fighting Measures

Suitable Extinguishing Media: Use foam, dry chemical, carbon dioxide or water fog for small fires
Unsuitable Extinguishing Media: Direct water jet
Fire Hazards: Vapors may form explosive mixtures with air. Can produce toxic fumes such as carbon monoxide and dioxide when burning.
Special Protective Equipment: Full protective clothing including self-contained breathing apparatus for fire fighters
Advice for Firefighters: Cool sealed containers with water spray to prevent bursting, evacuate area if unsafe. Prevent runoff into drains or watercourses.
Thermal Decomposition Products: Acrid smoke, carbon oxides, possible acrylic monomers

Accidental Release Measures

Personal Precautions: Evacuate area, ventilate, avoid inhalation and contact with skin or eyes. Wear chemical-resistant gloves, splash goggles, and appropriate protective clothing.
Environmental Precautions: Prevent entry into sewers, drains, or watercourses. Report release as required by local regulatory bodies.
Containment: Collect spillage using inert absorbent (sand, earth), place in suitable chemical waste container.
Cleaning Methods: Ventilate area, wash non-recoverable residue away with large amounts of water. Properly label and dispose containers.
Decontamination: Decontaminate tools and surfaces to prevent accidental polymerization.

Handling and Storage

Handling: Use only in well-ventilated areas with explosion-proof equipment. Avoid direct contact with skin, eyes, and clothing. Keep containers tightly sealed when not in use. Ground and bond containers before transfer.
Storage Conditions: Store in a cool, dry, well-ventilated facility away from heat, sparks, direct sunlight, and incompatible chemicals like oxidizers or acids. Use containers lined with compatible materials.
Technical Measures: Maintain proper labeling, keep container upright, use vapour containment systems
Incompatibility: Strong oxidizers, acids, bases, free radical initiators, reducing agents
Storage Temperature: Optimal below 30°C, avoid freezing or overheating

Exposure Controls and Personal Protection

Control Parameters: No established occupational exposure limits for octyl decyl acrylate; monitor for acrylic acid if present as impurity.
Engineering Controls: Use local exhaust, process enclosure, and explosion-proof ventilation to limit vapor accumulation.
Personal Protective Equipment: Chemical-resistant gloves (nitrile or neoprene), safety goggles, face shield for bulk work, flame-retardant antistatic garments, impervious footwear.
Respiratory Protection: Wear approved organic vapor respirator in the absence of adequate ventilation, especially for large spills or high vapor environments.
Environmental Controls: Prevent emissions, manage waste, inspect exhaust filtration systems regularly.
Hygiene Measures: Do not eat, drink, or smoke during use. Practice thorough hand washing before breaks and after work.

Physical and Chemical Properties

Appearance: Clear, colorless to pale yellow liquid
Odor: Faint, acrylate-like
Odor Threshold: Not determined
pH: Not applicable
Melting Point/Freezing Point: -58°C (-72°F)
Boiling Point: 266°C (511°F)
Flash Point: 115°C (239°F) (closed cup)
Evaporation Rate: Slower than ethyl ether
Flammability: Combustible
Upper/Lower Flammability: Data not determined
Vapor Pressure: <0.01 mmHg at 20°C
Vapor Density: Heavier than air
Relative Density: 0.87–0.90 g/cm³ at 25°C
Solubility: Practically insoluble in water; soluble in organic solvents
Partition Coefficient (n-octanol/water): >4 (high)
Auto-ignition Temperature: >250°C (482°F)
Decomposition Temperature: Not established
Viscosity: Low to moderate viscosity liquid

Stability and Reactivity

Chemical Stability: Stable at recommended storage and handling conditions
Polymerization: Inhibited with trace hydroquinone; uncontrolled polymerization possible from heat, light, peroxides, or contaminants
Reactivity: Reacts vigorously with strong oxidizers, acids, strong bases
Incompatible Materials: Free radical initiators, reducing agents, amines, strong acids or bases
Hazardous Decomposition Products: Acrid fumes, carbon monoxide, carbon dioxide, possible low molecular weight monomers
Conditions to Avoid: Excess heat, sunlight, sources of ignition, contamination by incompatible chemicals — preventive maintenance and monitoring essential.

Toxicological Information

Acute Toxicity: Low acute oral and dermal toxicity; eye and skin irritant
Inhalation: May cause mild respiratory tract irritation
Skin Contact: Redness, irritation, risk of allergic reactions in sensitized individuals
Eye Contact: Local irritation, watering, possible conjunctivitis
Ingestion: Not expected under normal use but may cause gastrointestinal discomfort, nausea, vomiting if swallowed
Chronic Effects: Sensitization after repeated exposure, rare but possible effects on respiratory health in occupational settings
Carcinogenicity: Not listed by ACGIH, IARC, NTP, OSHA
Reproductive Toxicity: No data demonstrating specific reproductive hazards
Mutagenicity: No evidence of mutagenic effects based on current data

Ecological Information

Ecotoxicity: Toxic to aquatic organisms, risk of bioaccumulation; long-lasting effects in aquatic ecosystems
Aquatic Toxicity: EC50 and LC50 values in the range below 10 mg/L (fish, daphnia and algae)
Persistence and Degradability: Not readily biodegradable; resists breakdown in water and soil
Bioaccumulation Potential: High log Kow value points to accumulation potential in aquatic life
Mobility in Soil: Low water solubility, likely to adsorb to soil and sediments
Other Adverse Effects: Not ozone depleting; does not contribute to global warming directly, but spills may impact wildlife

Disposal Considerations

Waste Treatment Methods: Incinerate in compliance with local, regional and national regulations; chemical incinerators equipped with afterburners and scrubbers are preferred
Disposal of Containers: Triple rinse empty containers before recycling or landfilling; puncture or crush for secure disposal
Special Precautions: Prevent contact with incompatible chemicals during waste handling; label as hazardous organic waste
Alternative Methods: Consult licenced chemical waste contractor for preferred technology; do not discharge to drains, surface waters, or ground
Residual Waste: Limit storage of large quantities of contaminated absorbents; segregate from municipal waste streams

Transport Information

UN Number: UN3082 (may vary if solution)
UN Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (contains octyl decyl acrylate)
Transport Hazard Class(es): Class 9 (Miscellaneous dangerous substances and articles)
Packing Group: III
Marine Pollutant: Yes
Special Precautions for Transport: Secure drums; avoid transport with oxidizers or foodstuffs; follow placarding and reporting rules for hazardous shipments
Transport Labels: Miscellaneous hazard warning label, environmental warning mark as required by IMDG, ADR, IATA
Additional Transport Information: Comply with all DOT, ICAO/IATA, IMDG codes for international shipments—ensure proper documentation and emergency procedures

Regulatory Information

US TSCA Status: Listed or complies with all requirements
EU REACH Status: Registration or pre-registration required over 1 metric ton/year, check with supplier for compliance statement
Canadian DSL/NDSL: Listed as required
SARA Title III: Not subject to Section 302, 304, or 313 reporting, but always confirm based on intended use
Right to Know: Subject to state and local community right-to-know laws (California, New Jersey, Pennsylvania, et al.)
GHS Compliance: Labeled in line with Globally Harmonized System and OSHA Hazard Communication Standard
Other International Inventories: Australian AICS, Japanese ENCS, Korean KECI, Chinese IECSC status available from importers
Labeling Requirements: Hazard pictograms, precautionary statements, composition information, emergency contact numbers included on primary and secondary packaging
Other Regulatory Remarks: Site operators must maintain training and chemical management tracking for emergency planning under relevant jurisdiction rules